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Issue 24, 2008
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Diphosphite ligands derived from carbohydrates as stabilizers for ruthenium nanoparticles: promising catalytic systems in arene hydrogenation

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Abstract

Ruthenium nanoparticles (RuNPs) were prepared through the hydrogenation of [Ru(COD)(COT)] (COD = 1,5-cyclooctadiene, COT = 1,3,5-cyclooctatriene) in the presence of diphosphites derived from carbohydrates as stabilizing agents, and interestingly, structural modifications of the diphosphite backbone were found to influence nanoparticle size and dispersity, as well as their catalytic activity in arene hydrogenation.

Graphical abstract: Diphosphite ligands derived from carbohydrates as stabilizers for ruthenium nanoparticles: promising catalytic systems in arene hydrogenation

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Publication details

The article was received on 11 Feb 2008, accepted on 17 Mar 2008 and first published on 09 Apr 2008


Article type: Communication
DOI: 10.1039/B802316F
Citation: Chem. Commun., 2008,0, 2759-2761
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    Diphosphite ligands derived from carbohydrates as stabilizers for ruthenium nanoparticles: promising catalytic systems in arene hydrogenation

    A. Gual, M. R. Axet, K. Philippot, B. Chaudret, A. Denicourt-Nowicki, A. Roucoux, S. Castillon and C. Claver, Chem. Commun., 2008, 0, 2759
    DOI: 10.1039/B802316F

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