Issue 27, 2008

A three-dimensional lanthanide-organic radical open-framework

Abstract

The reaction of a 3-connecting PTMTC radical with Tb(III) ions forms a three-dimensional open-framework with the formula [Tb(PTMTC)(DMF)3] (1), which associates a lattice complex T topology with large channels, guest-induced reversible crystal to amorphous transformations and ferromagnetic metal-radical interactions.

Graphical abstract: A three-dimensional lanthanide-organic radical open-framework

Supplementary files

Article information

Article type
Communication
Submitted
07 Feb 2008
Accepted
09 Apr 2008
First published
08 May 2008

Chem. Commun., 2008, 3160-3162

A three-dimensional lanthanide-organic radical open-framework

N. Roques, D. Maspoch, I. Imaz, A. Datcu, J. Sutter, C. Rovira and J. Veciana, Chem. Commun., 2008, 3160 DOI: 10.1039/B802196A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements