Issue 25, 2008
From the journal:

Chemical Communications

Synthesis of N,N-disubstituted phosphoramidatesvia a Lewis acid-catalyzed phosphorimidate rearrangement†‡

Ina Wilkening,a   Giuseppe del Signorea  and  Christian P. R. Hackenberger*a  

* Corresponding authors

a Freie Universität Berlin, Institut für Chemie und Biochemie, Takustraße 3, Germany
E-mail: hackenbe@chemie.fu-berlin.de
Fax: +49 30 838 52551
Tel: +49 30 838 52451

Abstract

A Lewis acid-catalyzed rearrangement of phosphorimidates allows a direct, high-yielding transformation of azides with commercially available phosphites into secondary phosphoramidates.

Graphical abstract: Synthesis of N,N-disubstituted phosphoramidatesvia a Lewis acid-catalyzed phosphorimidate rearrangement

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Article information

DOI
https://doi.org/10.1039/B802030B
Article type
Communication
Submitted
05 Feb 2008
Accepted
27 Mar 2008
First published
18 Apr 2008

Chem. Commun., 2008, 2932-2934

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Synthesis of N,N-disubstituted phosphoramidatesvia a Lewis acid-catalyzed phosphorimidate rearrangement

I. Wilkening, G. del Signore and C. P. R. Hackenberger, Chem. Commun., 2008, 2932 DOI: 10.1039/B802030B

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