An unusual dianion equivalent from acylsilanes for the synthesis of substituted β-keto esters

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Chemical Communications

Issue 16, 2008

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Chris V. Galliford and Karl A. Scheidt

Chem. Commun., 2008, 1926-1928

DOI: 10.1039/B801597J
Received 29 Jan 2008, Accepted 20 Feb 2008
First published on the web 10 Mar 2008

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The reaction of lithiated diazo esters with acylsilanes generates a remarkable intermediate en route to highly substituted β-keto esters.

Abstract from Methods in Organic Synthesis 2008

No abstract available