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Issue 19, 2008
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RhI-catalyzed aldol-type reaction of organonitriles under mild conditions

Akihiro Goto,a  Kohei Endo,ac  Yu Ukai,a  Stephan Irleb  and  Susumu Saito*ab 
Author affiliations

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya, Japan
E-mail: susumu@chem.nagoya-u.ac.jp
Fax: +81 52 789 5945
Tel: +81 52 789 5945

b Institute for Advanced Research, Nagoya University, Chikusa, Nagoya, Japan
E-mail: susumu@chem.nagoya-u.ac.jp
Fax: +81 52 788 6140
Tel: +81 52 788 6140

c Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Ohkubo, Shinjuku, Tokyo, Japan

Abstract

An aldol-type reaction of organonitriles with aldehydes was catalyzed by a RhI(OR) species under ambient conditions, and the reaction displayed a broad substrate scope with respect to both organonitrile and aldehyde components.

Graphical abstract: RhI-catalyzed aldol-type reaction of organonitriles under mild conditions

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Publication details

The article was received on 14 Jan 2008, accepted on 27 Feb 2008 and first published on 26 Mar 2008


Article type: Communication
DOI: 10.1039/B800634B
Citation: Chem. Commun., 2008, 2212-2214
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    RhI-catalyzed aldol-type reaction of organonitriles under mild conditions

    A. Goto, K. Endo, Y. Ukai, S. Irle and S. Saito, Chem. Commun., 2008, 2212
    DOI: 10.1039/B800634B

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