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Issue 16, 2008
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Unconventional thermodynamically stable cis isomer and trans to cis thermal isomerization in reversibly photoresponsive [0.0](3,3′)-azobenzenophane

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Abstract

Sterically hindered [0.0](3,3′)-azobenzenophane exhibits thermal trans-to-cisisomerization to the thermodynamically stable ciscis isomer, and reversible photochemical isomerization with good fatigue resistance.

Graphical abstract: Unconventional thermodynamically stable cis isomer and trans to cis thermal isomerization in reversibly photoresponsive [0.0](3,3′)-azobenzenophane

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Publication details

The article was received on 05 Dec 2007, accepted on 11 Feb 2008 and first published on 03 Mar 2008


Article type: Communication
DOI: 10.1039/B718813G
Citation: Chem. Commun., 2008,0, 1898-1900
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    Unconventional thermodynamically stable cis isomer and trans to cis thermal isomerization in reversibly photoresponsive [0.0](3,3′)-azobenzenophane

    Y. Norikane, R. Katoh and N. Tamaoki, Chem. Commun., 2008, 0, 1898
    DOI: 10.1039/B718813G

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