Issue 15, 2008
From the journal:

Chemical Communications

Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology†

Yue-Ling Bai,a   Jun Tao,*a   Rong-Bin Huang,a   Lan-Sun Zheng,a   Shao-Liang Zheng,*b   Kazuyoshi Oshidac  and  Yasuaki Einaga*c  

* Corresponding authors

a State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, Xiamen University, Xiamen 361005, People’s Republic of China
E-mail: taojun@xmu.edu.cn

b Department of Chemistry, University at Buffalo, the State University of New York, Buffalo, NY 14260-3000, USA
E-mail: chem9994@buffalo.edu

c Department of Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama, Japan
E-mail: einaga@chem.keio.ac.jp

Abstract

A three-dimensional mixed-valence iron complex with NiAs-type topology, [(FeIII3O)FeII(TA)6(H2O)3]·(ClO4)2(NO3)(EtOH)(H2O)2 (1, HTA = tetrazole-1H-acetic acid), shows spin-crossover behavior that was characterized via variable-temperature crystal structures, Mössbauer spectra and magnetic susceptibilities, the pressure effects on the transition behavior were also studied.

Graphical abstract: Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology

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Article information

DOI
https://doi.org/10.1039/B718456E
Article type
Communication
Submitted
29 Nov 2007
Accepted
21 Jan 2008
First published
11 Feb 2008

Chem. Commun., 2008, 1753-1755

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Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology

Y. Bai, J. Tao, R. Huang, L. Zheng, S. Zheng, K. Oshida and Y. Einaga, Chem. Commun., 2008, 1753 DOI: 10.1039/B718456E

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