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Issue 15, 2008
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Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology

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Abstract

A three-dimensional mixed-valence iron complex with NiAs-type topology, [(FeIII3O)FeII(TA)6(H2O)3]·(ClO4)2(NO3)(EtOH)(H2O)2 (1, HTA = tetrazole-1H-acetic acid), shows spin-crossover behavior that was characterized via variable-temperature crystal structures, Mössbauer spectra and magnetic susceptibilities, the pressure effects on the transition behavior were also studied.

Graphical abstract: Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology

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Publication details

The article was received on 29 Nov 2007, accepted on 21 Jan 2008 and first published on 11 Feb 2008


Article type: Communication
DOI: 10.1039/B718456E
Citation: Chem. Commun., 2008, 1753-1755
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    Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology

    Y. Bai, J. Tao, R. Huang, L. Zheng, S. Zheng, K. Oshida and Y. Einaga, Chem. Commun., 2008, 1753
    DOI: 10.1039/B718456E

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