Highly dispersed clay–polyolefin nanocomposites free of compatibilizers, via the in situ polymerization of α-olefins by clay-supported catalysts

Susannah L. Scott; Brian C. Peoples; Cathleen Yung; René S. Rojas; Vikram Khanna; Hironari Sano; Toru Suzuki; Fumihiko Shimizu

doi:10.1039/B718241D

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Chemical Communications

Issue 35, 2008

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Highly dispersed clay–polyolefin nanocomposites free of compatibilizers, via the in situ polymerization of α-olefins by clay-supported catalysts

Susannah L. Scott , Brian C. Peoples , Cathleen Yung , René S. Rojas , Vikram Khanna , Hironari Sano , Toru Suzuki and Fumihiko Shimizu

Chem. Commun., 2008, 4186-4188

DOI: 10.1039/B718241D
Received 27 Nov 2007, Accepted 27 Jun 2008
First published on the web 25 Jul 2008

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In situ polymerization by certain transition metal catalysts supported on and activated by acid-treated montmorillonite produces well-dispersed clay–polyolefin nanocomposites, without requiring either organic surfactants to be present in the clay phase or modification of the polyolefin structure.

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Supplementary Info

Clay treatment, polymerization procedures, measurement of flexural modulus and additional TEM images
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Articles By

Susannah L. Scott
Brian C. Peoples
Cathleen Yung
René S. Rojas
Vikram Khanna
Hironari Sano
Toru Suzuki
Fumihiko Shimizu

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Chemical Communications

Highly dispersed clay–polyolefin nanocomposites free of compatibilizers, via the in situ polymerization of α-olefins by clay-supported catalysts

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