‘Lock and key’ control of optical properties in a push–pull system

Brian J. Jordan; Michael A. Pollier; Yuval Ofir; Steven Joubanian; Jonathan G. Mehtala; Carsten Sinkel; Stuart T. Caldwell; Andrew Kennedy; Gouher Rabani; Graeme Cooke; Vincent M. Rotello

doi:10.1039/B718015B

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Chemical Communications

Issue 14, 2008

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‘Lock and key’ control of optical properties in a push–pull system

Brian J. Jordan , Michael A. Pollier , Yuval Ofir , Steven Joubanian , Jonathan G. Mehtala , Carsten Sinkel , Stuart T. Caldwell , Andrew Kennedy , Gouher Rabani , Graeme Cooke and Vincent M. Rotello

Chem. Commun., 2008, 1653-1655

DOI: 10.1039/B718015B
Received 25 Nov 2007, Accepted 11 Jan 2008
First published on the web 01 Feb 2008

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We report the modulation of the absorbance of a flavin push–pull derivative through specific recognition by a complementary diamidopyridine (DAP), shifting the flavin intramolecular charge transfer band by [similar] 30 nm.

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Chemical Communications

‘Lock and key’ control of optical properties in a push–pull system

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