Jump to main content
Jump to site search

Issue 15, 2008
Previous Article Next Article

An unusually stable octanuclear σ-mesityl-bridged µ4-oxo-copper(I) complex encapsulated by a pyrazolate-based compartmental ligand scaffold

Author affiliations

Abstract

A new compartmental pyrazole-derived chelating ligand, four equivalents of mesitylcopper and stoichiometric amounts of dioxygen lead to the formation of a remarkably stable organometallic framework that can be described as a heteroleptic O-centered cuprate anion [(MesCuI)4(µ4-O)]2 linked via σ-mesityl-bridges to two surrounding binuclear CuI-pyrazolate clamps.

Graphical abstract: An unusually stable octanuclear σ-mesityl-bridged µ4-oxo-copper(i) complex encapsulated by a pyrazolate-based compartmental ligand scaffold

Back to tab navigation

Supplementary files

Publication details

The article was received on 14 Nov 2007, accepted on 10 Jan 2008 and first published on 06 Feb 2008


Article type: Communication
DOI: 10.1039/B717571J
Citation: Chem. Commun., 2008, 1744-1746
  •   Request permissions

    An unusually stable octanuclear σ-mesityl-bridged µ4-oxo-copper(I) complex encapsulated by a pyrazolate-based compartmental ligand scaffold

    M. Stollenz, C. Große and F. Meyer, Chem. Commun., 2008, 1744
    DOI: 10.1039/B717571J

Search articles by author

Spotlight

Advertisements