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Issue 9, 2008
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Intramolecular cation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

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Abstract

NOEsy and fluorescence spectroscopy reveal that conversion of conformationally flexible (phenylalkyl)pyridines into their corresponding N-methyl-pyridinium iodides results in intramolecular π-stacking.

Graphical abstract: Intramolecular cation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

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Publication details

The article was received on 01 Nov 2007, accepted on 06 Dec 2007 and first published on 08 Jan 2008


Article type: Communication
DOI: 10.1039/B716937J
Citation: Chem. Commun., 2008,0, 1082-1084
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    Intramolecular cation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

    I. Richter, J. Minari, P. Axe, J. P. Lowe, T. D. James, K. Sakurai, S. D. Bull and J. S. Fossey, Chem. Commun., 2008, 0, 1082
    DOI: 10.1039/B716937J

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