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Issue 10, 2008
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Homogeneous polyhedral oligomeric silsesquioxane (POSS)-supported Pd–diimine complex and synthesis of polyethylenes end-tethered with a POSS nanoparticleviaethylene “living” polymerization

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Abstract

A POSS-supported Pd–diimine complex, an homogeneous analog of a supported catalyst, was synthesized and applied for the unique synthesis of narrow-distributed polyethylene chains containing an end-tethered POSS nanoparticle by ethylene “living” polymerization.

Graphical abstract: Homogeneous polyhedral oligomeric silsesquioxane (POSS)-supported Pd–diimine complex and synthesis of polyethylenes end-tethered with a POSS nanoparticleviaethylene “living” polymerization

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Publication details

The article was received on 01 Nov 2007, accepted on 17 Dec 2007 and first published on 10 Jan 2008


Article type: Communication
DOI: 10.1039/B716900K
Citation: Chem. Commun., 2008, 1178-1180
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    Homogeneous polyhedral oligomeric silsesquioxane (POSS)-supported Pd–diimine complex and synthesis of polyethylenes end-tethered with a POSS nanoparticleviaethylene “living” polymerization

    Y. Zhang and Z. Ye, Chem. Commun., 2008, 1178
    DOI: 10.1039/B716900K

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