Issue 6, 2008

A highly active and reusable copper(i)-tren catalyst for the “click” 1,3-dipolar cycloaddition of azides and alkynes

Abstract

The copper(I) complex [Cu(C186tren)]Br1 (C186tren = tris(2-dioctadecylaminoethyl)amine) which exhibits a good stability towards aerobic conditions is a versatile, highly reactive and recyclable catalyst for the Huisgen cycloaddition of azides with terminal or internal alkynes and is a useful catalyst for the preparation of “click” dendrimers.

Graphical abstract: A highly active and reusable copper(i)-tren catalyst for the “click” 1,3-dipolar cycloaddition of azides and alkynes

Supplementary files

Article information

Article type
Communication
Submitted
23 Oct 2007
Accepted
26 Nov 2007
First published
10 Dec 2007

Chem. Commun., 2008, 741-743

A highly active and reusable copper(I)-tren catalyst for the “click” 1,3-dipolar cycloaddition of azides and alkynes

N. Candelon, D. Lastécouères, A. K. Diallo, J. Ruiz Aranzaes, D. Astruc and J. Vincent, Chem. Commun., 2008, 741 DOI: 10.1039/B716306A

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