The structural determination of endohedral metallofullerene Gd@C82 by XANES

Lei Liu; Bin Gao; Wangsheng Chu; Dongliang Chen; Tiandou Hu; Chunru Wang; Lothar Dunsch; Augusto Marcelli; Yi Luo; Ziyu Wu

doi:10.1039/B714603E

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Chemical Communications

Issue 4, 2008

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The structural determination of endohedral metallofullerene Gd@C₈₂ by XANES

Lei Liu , Bin Gao , Wangsheng Chu , Dongliang Chen , Tiandou Hu , Chunru Wang , Lothar Dunsch , Augusto Marcelli , Yi Luo and Ziyu Wu

Chem. Commun., 2008, 474-476

DOI: 10.1039/B714603E
Received 21 Sep 2007, Accepted 06 Nov 2007
First published on the web 20 Nov 2007

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Although the Gd ion in Gd@C₈₂ has been shown to lie above the C–C bond on the C₂ axis as an anomalous structure from the MEM/Rietveld analysis, the present XANES study reveals that it lies above the hexagon on the C₂ axis as a normal structure, and Gd oscillates around its equilibrium position with an amplitude increasing with temperature increase.

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Chemical Communications

The structural determination of endohedral metallofullerene Gd@C₈₂ by XANES

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