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Issue 9, 2008
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Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate [Ph2BPtBu2]Cu(η1-N2CR2), [Ph2BPtBu2]Cu(CPh2), and [Ph2BPtBu2]Cu–N(CPh2)(NCPh2)

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Abstract

[Ph2BPtBu2]Cu–L complexes react with diazoalkanes to generate structurally unusual η1-diazoalkane adducts, a terminal carbene, and an η1-azine adduct.

Graphical abstract: Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BPtBu2]Cu(η1-N2CR2), [Ph2BPtBu2]Cu(CPh2), and [Ph2BPtBu2]Cu–N(CPh2)(NCPh2)

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Publication details

The article was received on 06 Sep 2007, accepted on 14 Dec 2007 and first published on 17 Jan 2008


Article type: Communication
DOI: 10.1039/B713687K
Citation: Chem. Commun., 2008, 1061-1063
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    Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate [Ph2BPtBu2]Cu(η1-N2CR2), [Ph2BPtBu2]Cu(CPh2), and [Ph2BPtBu2]Cu–N(CPh2)(NCPh2)

    N. P. Mankad and J. C. Peters, Chem. Commun., 2008, 1061
    DOI: 10.1039/B713687K

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