Aggregation-induced phosphorescent emission (AIPE) of iridium(III) complexes

Qiang Zhao; Lei Li; Fuyou Li; Mengxiao Yu; Zhipan Liu; Tao Yi; Chunhui Huang

doi:10.1039/B712416C

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Chemical Communications

Issue 6, 2008

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Aggregation-induced phosphorescent emission (AIPE) of iridium(III) complexes

Qiang Zhao , Lei Li , Fuyou Li , Mengxiao Yu , Zhipan Liu , Tao Yi and Chunhui Huang

Chem. Commun., 2008, 685-687

DOI: 10.1039/B712416C
Received 13 Aug 2007, Accepted 16 Nov 2007
First published on the web 30 Nov 2007
This article is part of the collection: Peking University Centenary Celebrations

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Abstract
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A novel aggregation-induced phosphorescent emission (AIPE) was observed for iridium(III) complexes. This interesting phenomenon was attributed to the intermolecular packing, resulting in a switch from the non-emissive ³LX excited state to the emissive ³MLLCT transition, which is confirmed by X-ray diffraction studies as well as theoretical calculations.

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Experimental procedures and characterization of all iridium(III) complexes
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Qiang Zhao
Lei Li
Fuyou Li
Mengxiao Yu
Zhipan Liu
Tao Yi
Chunhui Huang

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Chemical Communications

Aggregation-induced phosphorescent emission (AIPE) of iridium(III) complexes

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