Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

Ritu Ahuja; Sabuj Kundu; Alan S. Goldman; Maurice Brookhart; Brian C. Vicente; Susannah L. Scott

doi:10.1039/B712197K

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Chemical Communications

Issue 2, 2008

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Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

Ritu Ahuja , Sabuj Kundu , Alan S. Goldman , Maurice Brookhart , Brian C. Vicente and Susannah L. Scott

Chem. Commun., 2008, 253-255

DOI: 10.1039/B712197K
Received 08 Aug 2007, Accepted 18 Oct 2007
First published on the web 01 Nov 2007

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Tandem dehydrogenation–olefin-metathesis catalyst systems, comprising a pincer-ligated iridium-based alkane dehydrogenation catalyst and a molybdenum-based olefin-metathesis catalyst, are reported to effect the metathesis-cyclooligomerization of cyclooctane and cyclodecane to give cycloalkanes with various carbon numbers, predominantly multiples of the substrate carbon number, and polymers.

Abstract from Catalysts & Catalysed Reactions 2008

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Experimental details and procedures, full tables with product distribution for carbon number ≤ 40, GPC traces
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Ritu Ahuja
Sabuj Kundu
Alan S. Goldman
Maurice Brookhart
Brian C. Vicente
Susannah L. Scott

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Chemical Communications

Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

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