Issue 46, 2008
From the journal:

Chemical Communications

Diastereoisomeric bisphosphite ligands in the hydroformylation of octenes: rhodium catalysis and HP-NMR investigations†

Detlef Selent,*a   Wolfgang Baumann,a   Klaus-Diether Wieseb  and  Armin Börner*ac  

* Corresponding authors

a Leibniz-Institut für Katalyse an der Universität Rostock e.V., A.-Einstein-Str., 29a, Rostock, Germany
E-mail: detlef.selent@catalysis.de, armin.boerner@catalysis.de
Fax: +49381128151169

b Evonik Oxeno GmbH, Paul-Baumann-Str., 1, Marl, Germany

c Institut für Chemie der Universität Rostock, A.-Einstein-Str., 3, Rostock, Germany

Abstract

Diastereoisomeric hydroformylation catalysts show differences for the catalyst preformation pathway and a strongly reduced n-octene hydroformylation activity for the (S,S,R)-isomer.

Graphical abstract: Diastereoisomeric bisphosphite ligands in the hydroformylation of octenes: rhodium catalysis and HP-NMR investigations

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Article information

DOI
https://doi.org/10.1039/B814120G
Article type
Communication
Submitted
13 Aug 2008
Accepted
20 Oct 2008
First published
31 Oct 2008

Chem. Commun., 2008, 6203-6205

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Diastereoisomeric bisphosphite ligands in the hydroformylation of octenes: rhodium catalysis and HP-NMR investigations

D. Selent, W. Baumann, K. Wiese and A. Börner, Chem. Commun., 2008, 6203 DOI: 10.1039/B814120G

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