Issue 41, 2008
From the journal:

Chemical Communications

Competition between planar and central chiral control elements in nucleophilic addition to ferrocenyl imine derivatives†

Kévin M. Joly,a   Claire Wilson,a   Alexander J. Blake,a   James H. R. Tuckerb  and  Christopher J. Moody*a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: c.j.moody@nottingham.ac.uk

b School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UK

Abstract

Planar chirality associated with the ferrocene in ferrocenyl oximes and hydrazones bearing chiral auxiliaries effectively competes with or overrides the normally excellent stereocontrol afforded by the auxiliary in determining the diastereoselectivity of addition to the C[double bond, length as m-dash]N bond.

Graphical abstract: Competition between planar and central chiral control elements in nucleophilic addition to ferrocenyl imine derivatives

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B808045C
Article type
Communication
Submitted
12 May 2008
Accepted
28 Jul 2008
First published
12 Sep 2008

Chem. Commun., 2008, 5191-5193

Permissions

Request permissions

Competition between planar and central chiral control elements in nucleophilic addition to ferrocenyl imine derivatives

K. M. Joly, C. Wilson, A. J. Blake, J. H. R. Tucker and C. J. Moody, Chem. Commun., 2008, 5191 DOI: 10.1039/B808045C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements