Issue 20, 2008
From the journal:

Chemical Communications

Three-metal-center spin interactions through the intercalation of metal azaporphines and porphines into an organic pillared coordination box†

Kosuke Ono,a   Michito Yoshizawa,*ab   Tatsuhisa Kato*c  and  Makoto Fujita*a  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: mfujita@appchem.t.u-tokyo.ac.jp
Fax: +81 3-5841-7257
Tel: +81 3-5841-7259

b PRESTO, Japan Science and Technology Agency (JST)
E-mail: myoshiza@appchem.t.u-tokyo.ac.jp

c Department of Chemistry, Faculty of Science Josai University, 1-1 Keyakidai, Sakado, Saitama, Japan
E-mail: rik@josai.ac.jp
Fax: +81 49-271-7985
Tel: +81 49-271-7295

Abstract

Discrete homo Cu–Cu–Cu and hetero Cu–Pd–Cu or Cu–Co–Cu metal arrays are prepared within an organic-pillared coordination box by inserting M(II)-azaporphine/porphine cartridges (M = Cu(II), Pd(II) or Co(II)), where the metal arrays show unique spin interactions in ESR: in particular, Δms = 3 for the Cu–Cu–Cu array.

Graphical abstract: Three-metal-center spin interactions through the intercalation of metal azaporphines and porphines into an organic pillared coordination box

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Article information

DOI
https://doi.org/10.1039/B801701H
Article type
Communication
Submitted
31 Jan 2008
Accepted
07 Mar 2008
First published
11 Apr 2008

Chem. Commun., 2008, 2328-2330

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Three-metal-center spin interactions through the intercalation of metal azaporphines and porphines into an organic pillared coordination box

K. Ono, M. Yoshizawa, T. Kato and M. Fujita, Chem. Commun., 2008, 2328 DOI: 10.1039/B801701H

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