Issue 10, 2008
From the journal:

Chemical Communications

Stereoselective construction of nitrile-substituted cyclopropanes†‡

Justin R. Denton,a   Kevin Chenga  and  Huw M. L. Davies*a  

* Corresponding authors

a Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260-3000, USA
E-mail: hdavies@buffalo.edu
Fax: 716-645-6547
Tel: 716-645-6800X2186

Abstract

Nitrile-substituted cyclopropanes are readily synthesized in a stereocontrolled fashion from the intermolecular cyclopropanation between 2-diazo-2-phenylacetonitrile and electron-rich olefins, catalyzed by the chiral dirhodium complex, Rh2(S-PTAD)4.

Graphical abstract: Stereoselective construction of nitrile-substituted cyclopropanes

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Article information

DOI
https://doi.org/10.1039/B719175H
Article type
Communication
Submitted
13 Dec 2007
Accepted
21 Jan 2008
First published
07 Feb 2008

Chem. Commun., 2008, 1238-1240

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Stereoselective construction of nitrile-substituted cyclopropanes

J. R. Denton, K. Cheng and H. M. L. Davies, Chem. Commun., 2008, 1238 DOI: 10.1039/B719175H

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