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Issue 2, 2008
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Crabtree's catalyst revisited; Ligand effects on stability and durability

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Abstract

The extent of time-dependent deactivation of monophosphine monoamine iridium hydrogenation catalysts by trimer formation is strongly dependent on ligand structure; attempts to counter this process lead to the observation of an oligomerisation resistant catalyst.

Graphical abstract: Crabtree's catalyst revisited; Ligand effects on stability and durability

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Publication details

The article was received on 03 Aug 2007, accepted on 24 Sep 2007 and first published on 18 Oct 2007


Article type: Communication
DOI: 10.1039/B711979H
Citation: Chem. Commun., 2008,0, 199-201
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    Crabtree's catalyst revisited; Ligand effects on stability and durability

    Y. Xu, D. M. P. Mingos and J. M. Brown, Chem. Commun., 2008, 0, 199
    DOI: 10.1039/B711979H

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