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Issue 8, 2007
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Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna—towards photo-induced living radical polymerization

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Abstract

The photolysis of an alkoxyamine triad comprised of the 1-phenylethyl moiety, 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and 2-methyl-3-hydroxy quinoline leads to energy transfer from the quinoline moiety (antenna) and cleavage of the C–O alkoxyamine bond, suggesting its possible applications in low temperature living free radical polymerization.

Graphical abstract: Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna—towards photo-induced living radical polymerization

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Publication details

The article was received on 16 Apr 2007, accepted on 27 Jun 2007 and first published on 13 Jul 2007


Article type: Communication
DOI: 10.1039/B705671K
Citation: Photochem. Photobiol. Sci., 2007,6, 833-835
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    Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna—towards photo-induced living radical polymerization

    A. Goto, J. C. Scaiano and L. Maretti, Photochem. Photobiol. Sci., 2007, 6, 833
    DOI: 10.1039/B705671K

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