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Issue 22, 2007
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Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis

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Abstract

Approaches to the preparation of enantioenriched materials via catalytic methods that destroy stereogenic elements of a molecule are discussed. Although these processes often decrease overall molecular complexity, there are several notable advantages including material recycling, enantiodivergence and convergence, and increased substrate scope. Examples are accompanied by discussion of the critical design elements required for the success of these methods.

Graphical abstract: Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis

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Publication details

The article was received on 20 Jul 2007, accepted on 30 Aug 2007 and first published on 01 Oct 2007


Article type: Emerging Area
DOI: 10.1039/B711159M
Citation: Org. Biomol. Chem., 2007,5, 3571-3576
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    Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis

    J. T. Mohr, D. C. Ebner and B. M. Stoltz, Org. Biomol. Chem., 2007, 5, 3571
    DOI: 10.1039/B711159M

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