Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis

Justin T. Mohr; David C. Ebner; Brian M. Stoltz

doi:10.1039/B711159M

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Organic & Biomolecular Chemistry

Issue 22, 2007

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Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis

Justin T. Mohr , David C. Ebner and Brian M. Stoltz

Org. Biomol. Chem., 2007, 5, 3571-3576

DOI: 10.1039/B711159M
Received 20 Jul 2007, Accepted 30 Aug 2007
First published on the web 01 Oct 2007

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Abstract
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Approaches to the preparation of enantioenriched materials via catalytic methods that destroy stereogenic elements of a molecule are discussed. Although these processes often decrease overall molecular complexity, there are several notable advantages including material recycling, enantiodivergence and convergence, and increased substrate scope. Examples are accompanied by discussion of the critical design elements required for the success of these methods.

Abstract from Catalysts & Catalysed Reactions 2008

A review, with 26 references, of the preparation of enantioenriched materials via catalytic methods that destroy stereogenic groups; these methods have advantages including recycling, enantiodivergence and convergence, and increased substrate scope.

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Organic & Biomolecular Chemistry

Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis

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