Asymmetric catalysis for the construction of quaternary carbon centres: nucleophilic addition on ketones and ketimines

Olivier Riant; Jérôme Hannedouche

doi:10.1039/B617746H

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Organic & Biomolecular Chemistry

Issue 6, 2007

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Asymmetric catalysis for the construction of quaternary carbon centres: nucleophilic addition on ketones and ketimines

Olivier Riant and Jérôme Hannedouche

Org. Biomol. Chem., 2007, 5, 873-888

DOI: 10.1039/B617746H
Received 05 Dec 2006, First published on the web 05 Feb 2007

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There is a growing need in organic synthesis for efficient methodologies for the asymmetric synthesis of quaternary carbon centres. One of the most attractive and straightforward methods focuses on the use of asymmetric catalysis for the addition of various types of nucleophiles on prochiral ketones and ketimines. A view of the literature from this growing area of research will be presented in this review, with an emphasis on the pioneer works and milestones brought by the main players in this field.

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Abstract from Catalysts & Catalysed Reactions 2007

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Organic & Biomolecular Chemistry

Asymmetric catalysis for the construction of quaternary carbon centres: nucleophilic addition on ketones and ketimines

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