Issue 5, 2007
From the journal:

Organic & Biomolecular Chemistry

Virtually epimerization-free synthesis of peptide-α-thioesters†

Tyrone J. Hogenauer,a   Qianli Wang,b   Aditya K. Sanki,b   Amy J. Gammon,b   Cherie H. L. Chu,b   Clyde M. Kaneshiro,a   Yasuhiro Kajiharac  and  Katja Michael*a  

* Corresponding authors

a Department of Chemistry, University of Texas at El Paso, El Paso, TX, USA
E-mail: kmichael@utep.edu
Fax: +1 (915) 747-5748
Tel: +1 (915) 747-5240

b Department of Chemistry, University of Hawaii, Honolulu, HI, USA

c Graduate School of Integrated Science, Yokohama City University, Yokohama, Japan

Abstract

Under slightly basic or neutral reaction conditions peptide-α-thioesters are photochemically synthesized from peptide-α-nitroindoline precursors, either in solution, or by direct photorelease from a solid support.

Graphical abstract: Virtually epimerization-free synthesis of peptide-α-thioesters

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Article information

DOI
https://doi.org/10.1039/B618442A
Article type
Communication
Submitted
18 Dec 2006
Accepted
15 Jan 2007
First published
26 Jan 2007

Org. Biomol. Chem., 2007,5, 759-762

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Virtually epimerization-free synthesis of peptide-α-thioesters

T. J. Hogenauer, Q. Wang, A. K. Sanki, A. J. Gammon, C. H. L. Chu, C. M. Kaneshiro, Y. Kajihara and K. Michael, Org. Biomol. Chem., 2007, 5, 759 DOI: 10.1039/B618442A

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