Allenylzinc reagents: new trends and synthetic applications

Candice Botuha; Fabrice Chemla; Franck Ferreira; Alejandro Pérez-Luna; Brindaban Roy

doi:10.1039/B706541H

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New Journal of Chemistry

Issue 9, 2007

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Allenylzinc reagents: new trends and synthetic applications

Candice Botuha , Fabrice Chemla , Franck Ferreira , Alejandro Pérez-Luna and Brindaban Roy

New J. Chem., 2007, 31, 1552-1567

DOI: 10.1039/B706541H
Received 27 Apr 2007, Accepted 04 Jul 2007
First published on the web 27 Jul 2007

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Abstract
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The last developments in our research efforts involving allenylzinc reagents are summarized. These interesting organometallic compounds allow the stereoselective and enantioselective synthesis of acetylenic epoxides, aziridines and amino alcohols. Some synthetic applications of these highly functionalized substrates are also presented through the synthesis of homopropargylic alcohols and allenic ketones. Further applications in the total synthesis of heterocyclic natural products are also discussed.

Abstract from Methods in Organic Synthesis 2008

A review, with 187 references, summarising the latest developments in the use of allenylzinc reagents in stereoselective and enantioselective synthesis.

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Candice Botuha
Fabrice Chemla
Franck Ferreira
Alejandro Pérez-Luna
Brindaban Roy

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New Journal of Chemistry

Allenylzinc reagents: new trends and synthetic applications

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