Molecular tectonics: generation of 1-D interdigitated and 2-D interwoven helical silver coordination networks by oligoethylene glycol based tectons bearing two benzonitrile moieties

Julien Bourlier; Mir Wais Hosseini; Jean-Marc Planeix; Nathalie Kyritsakas

doi:10.1039/B611415F

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New Journal of Chemistry

Issue 1, 2007

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Molecular tectonics: generation of 1-D interdigitated and 2-D interwoven helical silver coordination networks by oligoethylene glycol based tectons bearing two benzonitrile moieties

Julien Bourlier , Mir Wais Hosseini , Jean-Marc Planeix and Nathalie Kyritsakas

New J. Chem., 2007, 31, 25-32

DOI: 10.1039/B611415F
Received 07 Aug 2006, Accepted 06 Nov 2006
First published on the web 07 Dec 2006

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Abstract
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Ligands based on oligoethylene glycol units bearing at their extremities benzonitrile groups behave in the crystalline phase as tectons and lead in the presence of silver cation to different coordination networks. Depending on the number of glycol units, 1-D stair type or 1-D interdigitated and 2-D interwoven architectures composed of helical strands are obtained.

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New Journal of Chemistry

Molecular tectonics: generation of 1-D interdigitated and 2-D interwoven helical silver coordination networks by oligoethylene glycol based tectons bearing two benzonitrile moieties

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