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Issue 5, 2007
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Structural–magnetic correlations on the first dinuclear spin crossover d4 system

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Abstract

The triple decker dinuclear Cr(II) salt [(η5-C5Me5)Cr(μ25-P5)Cr(η5-C5Me5)]+ (SbF6) has been structurally characterised by multiple temperature X-ray diffraction experiments from 290 K to 12 K. This material shows changes in its structural features which correlate with its magnetic response, including a structural transition with a change of symmetry from the orthorhombic space group Fddd to the monoclinic I2/a at ∼160 K and an abrupt rearrangement of electron density at ∼23 K

Graphical abstract: Structural–magnetic correlations on the first dinuclear spin crossover d4 system

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Publication details

The article was received on 22 Aug 2006, accepted on 27 Oct 2006 and first published on 14 Nov 2006


Article type: Paper
DOI: 10.1039/B612121G
Citation: J. Mater. Chem., 2007,17, 485-492
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    Structural–magnetic correlations on the first dinuclear spin crossover d4 system

    A. E. Goeta, J. A. K. Howard, A. K. Hughes, D. O'Hare and R. C. B. Copley, J. Mater. Chem., 2007, 17, 485
    DOI: 10.1039/B612121G

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