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Issue 41, 2007
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Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine

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Abstract

The reaction of 1,1,3,3-tetramethylguanidine (HTMG) with [UO2Cl2(THF)2] yielded [UO2Cl2(HTMG)2] 1, the first uranyl tetralkylguanidine adduct reported, further investigation led to the synthesis of [UO2(DBP)2(HTMG)2] 2 and [UO2(DBP-4-Me)2(HTMG)2] 3via the reaction of [UO2{N(SiMe3)2}2(THF)2] with HTMG and the appropriate aryl alcohol, HO-2,6-tBu2-4-RC6H2 (R = H, DBP; R = CH3, DBP-4-Me).

Graphical abstract: Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine

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Publication details

The article was received on 06 Aug 2007, accepted on 05 Sep 2007 and first published on 12 Sep 2007


Article type: Communication
DOI: 10.1039/B712054K
Citation: Dalton Trans., 2007, 4647-4649
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    Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine

    J. A. Bertke and S. D. Bunge, Dalton Trans., 2007, 4647
    DOI: 10.1039/B712054K

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