Insights into porphyrin chemistry provided by the microperoxidases, the haempeptides derived from cytochrome c

Helder M. Marques

doi:10.1039/B710940G

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Dalton Transactions

Issue 39, 2007

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Insights into porphyrin chemistry provided by the microperoxidases, the haempeptides derived from cytochrome c

Helder M. Marques

Dalton Trans., 2007, 4371-4385

DOI: 10.1039/B710940G
Received 17 Jul 2007, Accepted 15 Aug 2007
First published on the web 23 Aug 2007

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Abstract
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The water-soluble haem-containing peptides obtained by proteolytic digestion of cytochrome c, the microperoxidases, have been used to explore aspects of the chemistry of iron porphyrins, and as mimics for some reactions catalysed by the haemoproteins, including the reactions catalysed by the peroxidases and the cytochromes P450. The preparation of the microperoxidases, their physical and chemical properties including their electronic structure, the kinetics and thermodynamics of their reactions with ligands, electrochemical studies and examples of their uses as haemoproteins mimics, is reviewed.

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Dalton Transactions

Insights into porphyrin chemistry provided by the microperoxidases, the haempeptides derived from cytochrome c

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