Heterobimetallic coordination networks based on metallaporphyrins bearing four pyridine N-oxide groups as coordinating sites

Emmanuel Deiters; Véronique Bulach; Mir Wais Hosseini

doi:10.1039/B708302E

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Dalton Transactions

Issue 37, 2007

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Heterobimetallic coordination networks based on metallaporphyrins bearing four pyridine N-oxide groups as coordinating sites

Emmanuel Deiters , Véronique Bulach and Mir Wais Hosseini

Dalton Trans., 2007, 4126-4131

DOI: 10.1039/B708302E
Received 01 Jun 2007, Accepted 06 Jul 2007
First published on the web 30 Jul 2007

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Abstract
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The combination of two metallaporphyrin based tectons bearing four pyridyl-N-oxide groups with HgBr₂ or PbI₂ complexes leads to the formation of 3-D heterobimetallic coordination networks which were characterised in the crystalline phase by X-ray diffraction on single crystals. Both lone pairs of the oxygen atom of the pyridyl-N-oxide group participate in either coordination to the metal centre or in establishment of H-bonds with protic solvents.

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Dalton Transactions

Heterobimetallic coordination networks based on metallaporphyrins bearing four pyridine N-oxide groups as coordinating sites

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