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Issue 25, 2007
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Organoruthenium derivative of the cyclic [H7P8W48O184]33− anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27−

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Abstract

Reaction of [Ru(p-cymene)Cl2]2 with [H7P8W48O184]33− (P8W48) in aqueous acidic medium results in the organometallic derivative [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27− (1); in addition to the four {Ru(p-cymene)(H2O)} units, an unusual WO6 group with four equatorial, terminal ligands is also grafted to the crown-shaped P8W48 precursor.

Graphical abstract: Organoruthenium derivative of the cyclic [H7P8W48O184]33− anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27−

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Publication details

The article was received on 04 May 2007, accepted on 11 May 2007 and first published on 21 May 2007


Article type: Communication
DOI: 10.1039/B706762N
Citation: Dalton Trans., 2007,0, 2627-2630
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    Organoruthenium derivative of the cyclic [H7P8W48O184]33− anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27−

    S. S. Mal, N. H. Nsouli, M. H. Dickman and U. Kortz, Dalton Trans., 2007, 0, 2627
    DOI: 10.1039/B706762N

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