Pentafluorophenyl copper: aggregation and complexation phenomena, photoluminescence properties, and applications as reagent in organometallic synthesis

Frieder Jäkle

doi:10.1039/B704372D

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Dalton Transactions

Issue 27, 2007

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Pentafluorophenyl copper: aggregation and complexation phenomena, photoluminescence properties, and applications as reagent in organometallic synthesis

Frieder Jäkle

Dalton Trans., 2007, 2851-2858

DOI: 10.1039/B704372D
Received 22 Mar 2007, Accepted 10 May 2007
First published on the web 30 May 2007

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Recent advances in the chemistry of pentafluorophenyl copper are discussed, including the observation of strongly luminescent adducts with pyridine, the first successful structural characterization of an organocopper–arene complex, and the complexation with electron-rich transition metal complexes such as ferrocene derivatives. In addition, new applications in synthetic organometallic chemistry are discussed, which include the discovery of tin/copper exchange reactions for the preparation of organocopper compounds that are otherwise not readily accessible, and the selective transfer of the C₆F₅ groups to boron to form catalytically active and electronically interesting organoboron polymers.

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Dalton Transactions

Pentafluorophenyl copper: aggregation and complexation phenomena, photoluminescence properties, and applications as reagent in organometallic synthesis

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