The complexes [Et4N]3[Ln(η2-dcnm)6] (Ln = La, Ce, Nd, Gd, dcnm = dicyanonitrosomethanide) have discrete N, O 12-coordination owing to symmetrical chelation of the nitroso donor groups.
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Homoleptic 12-coordinate lanthanoids with η2-nitroso ligands
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School of Chemistry, Monash University, Clayton, Australia
E-mail: stuart.batten@sci.monash.edu.au ;
Fax: +61 (0)3 9905 4597 ;
Tel: +61 (0)3 9905 4606
E-mail: stuart.batten@sci.monash.edu.au ;
Fax: +61 (0)3 9905 4597 ;
Tel: +61 (0)3 9905 4606
Dalton Trans., 2007, 1371-1373
DOI: 10.1039/B702473H
Received 15 Feb 2007, Accepted 16 Feb 2007
First published online 27 Feb 2007
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