Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: easy formation of nido-carborane phosphonium zwitterions

Joseph A. Ioppolo; Jack K. Clegg; Louis M. Rendina

doi:10.1039/B700689F

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Dalton Transactions

Issue 20, 2007

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Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: easy formation of nido-carborane phosphonium zwitterions

Joseph A. Ioppolo , Jack K. Clegg and Louis M. Rendina

Dalton Trans., 2007, 1982-1985

DOI: 10.1039/B700689F
Received 16 Jan 2007, Accepted 20 Feb 2007
First published on the web 14 Mar 2007

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The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.

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Dalton Transactions

Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: easy formation of nido-carborane phosphonium zwitterions

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