Issue 5, 2007
From the journal:

Dalton Transactions

Arranging up to six ferrocene carboxamides around metal centres†

Domingo Salazar-Mendoza,a   Stéphane A. Baudron,*a   Mir Wais Hosseini,*a   Nathalie Kyritsakasa  and  André De Ciana  

* Corresponding authors

a Laboratoire de Chimie de Coordination Organique (UMR CNRS 7140), Université Louis Pasteur, Institut Le Bel, 4 rue Blaise Pascal, Strasbourg, France
E-mail: sbaudron@chimie.u-strasbg.fr, hosseini@chimie.u-strasbg.fr
Fax: +33 390241325
Tel: +33 390241323

Abstract

Ferrocene carboxamide, FcCONH2, forms homo- and heteroleptic complexes with Co(II), Ni(II) and Cu(II) via coordination of its carbonyl group. Whereas for both Co(II) and Ni(II), hexaferrocenyl complexes are obtained in the presence of BF4− anion, in the case of Cu(II) a tetraferrocenyl species is observed in the presence of triflate anion.

Graphical abstract: Arranging up to six ferrocene carboxamides around metal centres

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Article information

DOI
https://doi.org/10.1039/B617112P
Article type
Paper
Submitted
22 Nov 2006
Accepted
04 Dec 2006
First published
22 Dec 2006

Dalton Trans., 2007, 565-569

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Arranging up to six ferrocene carboxamides around metal centres

D. Salazar-Mendoza, S. A. Baudron, M. W. Hosseini, N. Kyritsakas and A. De Cian, Dalton Trans., 2007, 565 DOI: 10.1039/B617112P

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