Arranging up to six ferrocene carboxamides around metal centres

Domingo Salazar-Mendoza; Stéphane A. Baudron; Mir Wais Hosseini; Nathalie Kyritsakas; André De Cian

doi:10.1039/B617112P

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Dalton Transactions

Issue 5, 2007

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Arranging up to six ferrocene carboxamides around metal centres

Domingo Salazar-Mendoza , Stéphane A. Baudron , Mir Wais Hosseini , Nathalie Kyritsakas and André De Cian

Dalton Trans., 2007, 565-569

DOI: 10.1039/B617112P
Received 22 Nov 2006, Accepted 04 Dec 2006
First published on the web 22 Dec 2006

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Abstract
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Ferrocene carboxamide, FcCONH₂, forms homo- and heteroleptic complexes with Co(II), Ni(II) and Cu(II) via coordination of its carbonyl group. Whereas for both Co(II) and Ni(II), hexaferrocenyl complexes are obtained in the presence of BF₄⁻ anion, in the case of Cu(II) a tetraferrocenyl species is observed in the presence of triflate anion.

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Domingo Salazar-Mendoza
Stéphane A. Baudron
Mir Wais Hosseini
Nathalie Kyritsakas
André De Cian

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Dalton Transactions

Arranging up to six ferrocene carboxamides around metal centres

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