Issue 31, 2007
From the journal:

Dalton Transactions

Characterization and alkaneoxidation activity of a diastereopure seven-coordinate iron(iii) alkylperoxo complex†

Silvia Gosiewska,a   Hjalmar P. Permentier,b   Andries P. Bruins,b   Gerard van Kotena  and  Robertus J. M. Klein Gebbink*a  

* Corresponding authors

a Organic Chemistry and Catalysis, Utrecht University, Padualaan 8, CH Utrecht, The Netherlands
E-mail: r.j.m.kleingebbink@chem.uu.nl
Fax: +31 30252 3615
Tel: +31 30253 3054

b University of Groningen, Mass Spectrometry Core Facility, A. Deusinglaan 1, AV Groningen, The Netherlands
Fax: +31 50363 8347
Tel: +31 50363 3262

Abstract

Spectroscopic characterization and alkane oxidation studies of a diastereopure seven-coordinate high-spin iron(III) alkylperoxo complex based on the chiral N,N′,N-bis(L-prolinate)pyridine ligand Py(ProMe)2 (1) are reported.

Graphical abstract: Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(iii) alkylperoxo complex

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DOI
https://doi.org/10.1039/B706604J
Article type
Communication
Submitted
01 May 2007
Accepted
24 May 2007
First published
26 Jun 2007

Dalton Trans., 2007, 3365-3368

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Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III) alkylperoxo complex

S. Gosiewska, H. P. Permentier, A. P. Bruins, G. van Koten and R. J. M. K. Gebbink, Dalton Trans., 2007, 3365 DOI: 10.1039/B706604J

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