Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds

Miguel Rubio; Andrés Suárez; Diego del Río; Agustín Galindo; Eleuterio Álvarez; Antonio Pizzano

doi:10.1039/B617164H

Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds

Miguel Rubio,^a Andrés Suárez,^a Diego del Río,^a Agustín Galindo,*^b Eleuterio Álvarez^a and Antonio Pizzano*^a

* Corresponding authors

^a Instituto de Investigaciones Químicas, Consejo Superior de Investigaciones Científicas and Universidad de Sevilla, Avda Américo Vespucio no. 49, Isla de la Cartuja, Sevilla, Spain
E-mail: pizzano@iiq.csic.es
Fax: 34 954460565
Tel: 34 954489556

^b Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo 553, Sevilla, Spain
E-mail: galindo@us.es
Fax: 34 954557153
Tel: 34 954557161

Abstract

Square-planar ethylene rhodium derivatives bearing pincer diphosphite ligands have been prepared and characterized, they display a rare in-plane coordination which, based on DFT calculations, has been mainly attributed to steric effects.

Supplementary files

Publication details

The article was received on 23 Nov 2006, accepted on 05 Dec 2006 and first published on 13 Dec 2006

Article type: Communication

DOI: 10.1039/B617164H

Citation: Dalton Trans., 2007,0, 407-409

Request permissions
Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds

M. Rubio, A. Suárez, D. del Río, A. Galindo, E. Álvarez and A. Pizzano, Dalton Trans., 2007, 0, 407
DOI: 10.1039/B617164H
If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using RightsLink. Go to our Instructions for using RightsLink page for details.

Authors contributing to RSC publications (journal articles, books or book chapters) do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:
For reproduction of material from NJC:
Reproduced from Ref. XX with permission from the Centre National de la Recherche Scientifique (CNRS) and The Royal Society of Chemistry.

For reproduction of material from PCCP:
Reproduced from Ref. XX with permission from the PCCP Owner Societies.

For reproduction of material from PPS:
Reproduced from Ref. XX with permission from the European Society for Photobiology, the European Photochemistry Association, and The Royal Society of Chemistry.

For reproduction of material from all other RSC journals and books:
Reproduced from Ref. XX with permission from The Royal Society of Chemistry.
If the material has been adapted instead of reproduced from the original RSC publication "Reproduced from" can be substituted with "Adapted from".

In all cases the Ref. XX is the XXth reference in the list of references.

If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. contained in this article in third party publications or in a thesis or dissertation provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:
For reproduction of material from NJC:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC

For reproduction of material from PCCP:
[Original citation] - Reproduced by permission of the PCCP Owner Societies

For reproduction of material from PPS:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC

For reproduction of material from all other RSC journals:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry
If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Dalton Transactions

Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds

Abstract

Supplementary files

Publication details

Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds

Search articles by author

Spotlight

Advertisements