Syntheses and solid state structures of hybrid d10 metal–organic frameworks based on methylenediisophthalic acid (H4MDIP)

Xianying Duan; Yizhi Li; Yang Su; Shuangquan Zang; Chengjian Zhu; Qingjin Meng

doi:10.1039/B618613K

Syntheses and solid state structures of hybrid d¹⁰ metal–organic frameworks based on methylenediisophthalic acid (H₄MDIP)

Xianying Duan,^a Yizhi Li,^a Yang Su,^a Shuangquan Zang,^a Chengjian Zhu^a and Qingjin Meng*^a

* Corresponding authors

^a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China
E-mail: mengqj@nju.edu.cn
Tel: 86-25-83597266

Abstract

Four novel hybrid d¹⁰ metal complexes [Zn(H₂MDIP)(4,4′-bpy)_0.5]_n1 (4,4′-bpy = 4,4′-bipyridine, H₄MDIP = methylenediisophthalic acid), [Zn₂(MDIP)(bix)·H₂O]_n2 [bix = 1,4-bis(imidazol-1-ylmethyl)-benzene], {[Cd(H₂MDIP)(H₂O)]₂·H₂O}_n3, {[Cd₂(MDIP)(H₂O)₂(en)₂]·2H₂O}_n4 (en = ethylenediamine) based on tetracarboxylate acid were synthesized and their structures were determined by X-ray single-crystal diffraction. Complexes 1–2 are 2D grid and undulated structures with four-coordinated Zn²⁺ ions, respectively; 3–4 are 2D grid and double-sheet structures with six-coordinated Cd²⁺ ions, respectively. MDIP in complexes 1 and 3 act as V-shaped and Y-shaped ligands, respectively, yet in 2 and 4 MDIP act as similar X-shaped ligands. Diverse topologies, thermal and luminescent properties of complexes 1–4 have also been investigated.

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Publication details

The article was received on 20 Dec 2006, accepted on 02 May 2007 and first published on 18 May 2007

Article type: Paper

DOI: 10.1039/B618613K

Citation: CrystEngComm, 2007,9, 758-766

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Syntheses and solid state structures of hybrid d¹⁰ metal–organic frameworks based on methylenediisophthalic acid (H₄MDIP)

X. Duan, Y. Li, Y. Su, S. Zang, C. Zhu and Q. Meng, CrystEngComm, 2007, 9, 758
DOI: 10.1039/B618613K
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CrystEngComm

Syntheses and solid state structures of hybrid d¹⁰ metal–organic frameworks based on methylenediisophthalic acid (H₄MDIP)

Abstract

Supplementary files

Publication details

Syntheses and solid state structures of hybrid d¹⁰ metal–organic frameworks based on methylenediisophthalic acid (H₄MDIP)

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