Electrochemical control of surface properties using a quinone-functionalized monolayer: effects of donor–acceptor complexes

Agnieszka Wieckowska; Adam B. Braunschweig; Itamar Willner

doi:10.1039/B710540A

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Chemical Communications

Issue 38, 2007

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Electrochemical control of surface properties using a quinone-functionalized monolayer: effects of donor–acceptor complexes

Agnieszka Wieckowska , Adam B. Braunschweig and Itamar Willner

Chem. Commun., 2007, 3918-3920

DOI: 10.1039/B710540A
Received 11 Jul 2007, Accepted 31 Jul 2007
First published on the web 20 Aug 2007

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Abstract
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A benzoquinone monolayer-functionalized electrode reveals electrochemically or chemically controlled wettability; the hydrophobicity of the hydroquinone-modified surface is enhanced by the presence of a donor–acceptor complex with N,N′-dimethyl-4,4′-bipyridinium as the π-electron acceptor.

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Surface preparation and characterisation, contact angle and force measurements
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Chemical Communications

Electrochemical control of surface properties using a quinone-functionalized monolayer: effects of donor–acceptor complexes

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