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Issue 47, 2007
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Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

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Abstract

A four-membered cyclic intramolecular phosphane–borane adduct activates dihydrogen to yield the respective ethylene-bridged zwitterionic phosphonium–hydridoborate system, which reduces benzaldehyde.

Graphical abstract: Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

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Publication details

The article was received on 10 Jul 2007, accepted on 13 Sep 2007 and first published on 02 Oct 2007


Article type: Communication
DOI: 10.1039/B710475H
Citation: Chem. Commun., 2007,0, 5072-5074
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    Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

    P. Spies, G. Erker, G. Kehr, K. Bergander, R. Fröhlich, S. Grimme and D. W. Stephan, Chem. Commun., 2007, 0, 5072
    DOI: 10.1039/B710475H

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