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Issue 43, 2007
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Dynamic kinetic and kinetic resolution of N-Boc-2-lithiopiperidine

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Abstract

Asymmetric substitution of 2-lithiopiperidines can be achieved by dynamic resolution; the organolithium is formed as a racemic mixture by proton abstraction (or tin–lithium exchange) and is resolved in the presence of a chiral ligand.

Graphical abstract: Dynamic kinetic and kinetic resolution of N-Boc-2-lithiopiperidine

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Publication details

The article was received on 03 Jul 2007, accepted on 04 Sep 2007 and first published on 12 Sep 2007


Article type: Communication
DOI: 10.1039/B710066C
Citation: Chem. Commun., 2007,0, 4534-4536
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    Dynamic kinetic and kinetic resolution of N-Boc-2-lithiopiperidine

    I. Coldham, J. J. Patel, S. Raimbault and D. T. E. Whittaker, Chem. Commun., 2007, 0, 4534
    DOI: 10.1039/B710066C

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