Molecular tectonics: polymorphism and enhancement of network dimensionality by a combination of primary and secondary hydrogen bond sites

Pierre Dechambenoit; Sylvie Ferlay; Mir Wais Hosseini; Nathalie Kyritsakas

doi:10.1039/B708997J

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Chemical Communications

Issue 44, 2007

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Molecular tectonics: polymorphism and enhancement of network dimensionality by a combination of primary and secondary hydrogen bond sites

Pierre Dechambenoit , Sylvie Ferlay , Mir Wais Hosseini and Nathalie Kyritsakas

Chem. Commun., 2007, 4626-4628

DOI: 10.1039/B708997J
Received 14 Jun 2007, Accepted 29 Aug 2007
First published on the web 24 Sep 2007

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Abstract
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A dicationic tecton bearing four NH and two OH groups, as primary and secondary hydrogen bond donor sites, respectively, leads, in the presence of [M(CN)₄]²⁻ anions, to the formation of polymorphic 2- and 3-D hydrogen-bonded networks.

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Chemical Communications

Molecular tectonics: polymorphism and enhancement of network dimensionality by a combination of primary and secondary hydrogen bond sites

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