Design and synthesis of thiazoline–thiazole hybrid macrocycles possessing strong binding affinity to Pb2+ and Cd2+

Fu She Han; Hidetoshi Tokuyama; Tohru Fukuyama

doi:10.1039/B707904D

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Chemical Communications

Issue 33, 2007

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Design and synthesis of thiazoline–thiazole hybrid macrocycles possessing strong binding affinity to Pb²⁺ and Cd²⁺

Fu She Han , Hidetoshi Tokuyama and Tohru Fukuyama

Chem. Commun., 2007, 3444-3446

DOI: 10.1039/B707904D
Received 24 May 2007, Accepted 04 Jul 2007
First published on the web 25 Jul 2007

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Abstract
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Thiazoline–thiazole hybrid macrocycles were synthesized via head-to-tail cyclooligomerization. The macrocycle consisting of eight heterocyclic subunits displays high binding affinity to the heavy metal toxins Pb²⁺ and Cd²⁺.

Supplementary Info

Structural characterization of macrocycles 7 and 8, UV-vis and ¹H-NMR titrations
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Chemical Communications

Design and synthesis of thiazoline–thiazole hybrid macrocycles possessing strong binding affinity to Pb²⁺ and Cd²⁺

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