Regioselectivity and enantioselectivity in nickel-catalysed reductive coupling reactions of alkynes

Ryan M. Moslin; Karen Miller-Moslin; Timothy F. Jamison

doi:10.1039/B707737H

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Chemical Communications

Issue 43, 2007

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Regioselectivity and enantioselectivity in nickel-catalysed reductive coupling reactions of alkynes

Ryan M. Moslin , Karen Miller-Moslin and Timothy F. Jamison

Chem. Commun., 2007, 4441-4449

DOI: 10.1039/B707737H
Received 22 May 2007, Accepted 18 Jun 2007
First published on the web 03 Jul 2007

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Nickel-catalysed reductive coupling reactions of alkynes have emerged as powerful synthetic tools for the selective preparation of functionalized alkenes. One of the greatest challenges associated with these transformations is control of regioselectivity. Recent work from our laboratory has provided an improved understanding of several of the factors governing regioselectivity in these reactions, and related studies have revealed that the reaction mechanism can differ substantially depending on the ligand employed. A discussion of stereoselective transformations and novel applications of nickel catalysis in coupling reactions of alkynes is also included.

Abstract from Methods in Organic Synthesis 2008

A review, with 47 references, of the regioselective nickel catalysed reductive coupling of alkynes to produce functionalised alkenes.

Abstract from Catalysts & Catalysed Reactions 2008

A review, with 47 references, of this laboratory's work on nickel-catalysed reductive coupling of alkynes, detailing factors governing the regioselectivity, and the effect of the catalyst ligand on the reaction mechanism.

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Chemical Communications

Regioselectivity and enantioselectivity in nickel-catalysed reductive coupling reactions of alkynes

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