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Issue 39, 2007
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Consecutive palladium-catalyzed Hiyama–Heck reactions in aqueous media under ligand-free conditions

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Abstract

Symmetric and asymmetric (E)-1,2-diarylethenes are synthesized from aryl bromides by consecutive one-pot Hiyama–Heck reactions carried out in water and under air; the only additives required are sodium hydroxide, palladium acetate and poly(ethylene glycol), and the products are isolable in many cases by simple filtration of the water solution.

Graphical abstract: Consecutive palladium-catalyzed Hiyama–Heck reactions in aqueous media under ligand-free conditions

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Publication details

The article was received on 21 May 2007, accepted on 03 Jul 2007 and first published on 25 Jul 2007


Article type: Communication
DOI: 10.1039/B707583A
Citation: Chem. Commun., 2007,0, 4056-4058
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    Consecutive palladium-catalyzed Hiyama–Heck reactions in aqueous media under ligand-free conditions

    Á. Gordillo, E. de Jesús and C. López-Mardomingo, Chem. Commun., 2007, 0, 4056
    DOI: 10.1039/B707583A

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