Probing the stable G-quadruplex transition using quencher-free end-stacking ethynyl pyrene–adenosine

Young Jun Seo; Il Joon Lee; Jeong Wu Yi; Byeang Hyean Kim

doi:10.1039/B707278C

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Chemical Communications

Issue 27, 2007

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Probing the stable G-quadruplex transition using quencher-free end-stacking ethynyl pyrene–adenosine

Young Jun Seo , Il Joon Lee , Jeong Wu Yi and Byeang Hyean Kim

Chem. Commun., 2007, 2817-2819

DOI: 10.1039/B707278C
Received 14 May 2007, Accepted 05 Jun 2007
First published on the web 18 Jun 2007

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Abstract
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Pyrene-modified adenosines in the dangling positions of G-rich oligodeoxynucleotides undergo π-stacking in their G-quadruplex formation, but not in their single strands, which can be characterized by fluorescence λ_max changes that occur on stacking.

Supplementary Info

MALDI-TOF mass data of the ODNs, melting temperatures, absorption and fluorescence spectra
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Chemical Communications

Probing the stable G-quadruplex transition using quencher-free end-stacking ethynyl pyrene–adenosine

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