A molecular gate based on a porphyrin and a silver lock

Aurélie Guenet; Ernest Graf; Nathalie Kyritsakas; Lionel Allouche; Mir Wais Hosseini

doi:10.1039/B706527B

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Chemical Communications

Issue 28, 2007

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A molecular gate based on a porphyrin and a silver lock

Aurélie Guenet , Ernest Graf , Nathalie Kyritsakas , Lionel Allouche and Mir Wais Hosseini

Chem. Commun., 2007, 2935-2937

DOI: 10.1039/B706527B
Received 01 May 2007, Accepted 04 Jun 2007
First published on the web 20 Jun 2007

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A Sn(IV) metallaporphyrin bearing a 4-pyridyl group on one meso position and a handle equipped also with a pyridyl unit functions in solution as a molecular gate in the presence of silver cation: the complexation–decomplexation of Ag(I) corresponds to the opening and closing motions of the gate.

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Aurélie Guenet
Ernest Graf
Nathalie Kyritsakas
Lionel Allouche
Mir Wais Hosseini

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Chemical Communications

A molecular gate based on a porphyrin and a silver lock

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