Issue 22, 2007
From the journal:

Chemical Communications

A planar chelating bitriazole N-heterocyclic carbeneligand and its rhodium(iii) and dirhodium(ii) complexes†

Macarena Poyatos,a   William McNamara,a   Chris Incarvito,a   Eduardo Peris*b  and  Robert H. Crabtree*a  

* Corresponding authors

a Yale Chemistry Department, 225 Prospect St., New Haven, CT, USA
E-mail: robert.crabtree@yale.edu
Fax: +1 203 432 6144
Tel: +1 203 432 3915

b Dpto. de Química Inorgánica y Orgánica, Universitat Jaume I, Av. Sos Bainat s/n, Castellón, Spain
E-mail: eperis@qio.uji.es
Fax: +34 964 728214
Tel: +34 964 728243

Abstract

The new ligand bitriazole-2-ylidene (bitz) reliably chelates to Rh under very mild conditions, providing an NHC analogue of 2,2′-dipyridyl ligand.

Graphical abstract: A planar chelating bitriazole N-heterocyclic carbene ligand and its rhodium(iii) and dirhodium(ii) complexes

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Article information

DOI
https://doi.org/10.1039/B705246D
Article type
Communication
Submitted
10 Apr 2007
Accepted
30 Apr 2007
First published
14 May 2007

Chem. Commun., 2007, 2267-2269

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A planar chelating bitriazole N-heterocyclic carbene ligand and its rhodium(III) and dirhodium(II) complexes

M. Poyatos, W. McNamara, C. Incarvito, E. Peris and R. H. Crabtree, Chem. Commun., 2007, 2267 DOI: 10.1039/B705246D

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