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Issue 22, 2007
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A planar chelating bitriazole N-heterocyclic carbene ligand and its rhodium(III) and dirhodium(II) complexes

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Abstract

The new ligand bitriazole-2-ylidene (bitz) reliably chelates to Rh under very mild conditions, providing an NHC analogue of 2,2′-dipyridyl ligand.

Graphical abstract: A planar chelating bitriazole N-heterocyclic carbene ligand and its rhodium(iii) and dirhodium(ii) complexes

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Publication details

The article was received on 10 Apr 2007, accepted on 30 Apr 2007 and first published on 14 May 2007


Article type: Communication
DOI: 10.1039/B705246D
Citation: Chem. Commun., 2007,0, 2267-2269
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    A planar chelating bitriazole N-heterocyclic carbene ligand and its rhodium(III) and dirhodium(II) complexes

    M. Poyatos, W. McNamara, C. Incarvito, E. Peris and R. H. Crabtree, Chem. Commun., 2007, 0, 2267
    DOI: 10.1039/B705246D

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